Cuprophilic and pi-stacking interactions in the formation of supramolecular stacks from dicoordinate organocopper complexes.
نویسندگان
چکیده
The unsupported organocopper pyridine complexes C6F5Cu(py) (2) and [C6F5Cu]2(4,4'-bipy) (3) form supramolecular structures that are unprecedented in organocopper chemistry; one-dimensional chains of copper atoms with Cu...Cu distances of 2.8924(3) angstroms in the blue-luminescent complex are likely associated with cuprophilic interactions, whereas multiple perfluoroarene-arene interactions dominate in the supramolecular assembly of 3.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 13 شماره
صفحات -
تاریخ انتشار 2005